1 00:00:00,000 --> 00:00:00,870 2 00:00:00,870 --> 00:00:05,150 SAL: The notion of a half-life is useful, if we're dealing 3 00:00:05,150 --> 00:00:07,950 with increments of time that are multiples of a half-life. 4 00:00:07,950 --> 00:00:11,980 For example, where time equals zero, we 5 00:00:11,980 --> 00:00:14,190 have 100% of our substance. 6 00:00:14,190 --> 00:00:18,580 Then after time equals one half-life, we'd have 50% of 7 00:00:18,580 --> 00:00:19,550 our substance. 8 00:00:19,550 --> 00:00:23,350 At time is equal to two half-lives, we'd have 25% of 9 00:00:23,350 --> 00:00:25,440 our substance, and so on and so forth. 10 00:00:25,440 --> 00:00:28,300 So if I say that three half-lives have gone by-- in 11 00:00:28,300 --> 00:00:30,740 the case of carbon that would be, what, roughly 15,000 12 00:00:30,740 --> 00:00:34,840 years-- I can tell you roughly, or almost exactly, 13 00:00:34,840 --> 00:00:39,030 what percentage of my original element I still have. In the 14 00:00:39,030 --> 00:00:41,390 case of carbon-14, I'll tell you what percentage of my 15 00:00:41,390 --> 00:00:44,570 original carbon-14 has not decayed into nitrogen, as yet, 16 00:00:44,570 --> 00:00:45,880 nitrogen-14. 17 00:00:45,880 --> 00:00:49,110 And that's useful, but what if I care about how much carbon I 18 00:00:49,110 --> 00:00:52,460 have after 1/2 a year, or after 1/2 a half life, or 19 00:00:52,460 --> 00:00:54,510 after three billion years, or after 10 minutes? 20 00:00:54,510 --> 00:00:56,980 What if I want a general function. 21 00:00:56,980 --> 00:01:00,190 A general function, as a function of time, that tells 22 00:01:00,190 --> 00:01:05,430 me the number, or the amount, of my decaying substance I 23 00:01:05,430 --> 00:01:07,670 have. So that's what we're going to do in this video. 24 00:01:07,670 --> 00:01:09,460 And it's going to be a little mathy, but I think the math is 25 00:01:09,460 --> 00:01:12,180 pretty straightforward, especially if you've taken a 26 00:01:12,180 --> 00:01:14,030 first-year course in calculus. 27 00:01:14,030 --> 00:01:16,650 And this is actually a pretty neat application of it. 28 00:01:16,650 --> 00:01:20,050 So let's just think a little bit about the rate of change, 29 00:01:20,050 --> 00:01:23,090 or the probability, or the number particles that are 30 00:01:23,090 --> 00:01:24,390 changing at any given time. 31 00:01:24,390 --> 00:01:28,910 So if we say, the difference or change in our number of 32 00:01:28,910 --> 00:01:32,750 particles, or the amount of particles, in any very small 33 00:01:32,750 --> 00:01:38,140 period of time, what's this going to be dependent on? 34 00:01:38,140 --> 00:01:39,850 This is the number particles we have in a 35 00:01:39,850 --> 00:01:40,860 given period time. 36 00:01:40,860 --> 00:01:43,160 This is our rate of change. 37 00:01:43,160 --> 00:01:46,420 So one thing, we know that our rate of change is going down. 38 00:01:46,420 --> 00:01:48,960 We know it's a negative number. 39 00:01:48,960 --> 00:01:51,390 We know that, in the case of radioactive decay, I could do 40 00:01:51,390 --> 00:01:55,150 the same exercise with compounding growth, where I 41 00:01:55,150 --> 00:01:57,470 would say, oh no, it's not a negative number, that our 42 00:01:57,470 --> 00:02:00,680 growth is dependent on how much we have. In this case the 43 00:02:00,680 --> 00:02:03,800 amount we're decaying is proportional, but it's going 44 00:02:03,800 --> 00:02:07,400 to be the negative of how much of the actual compound we 45 00:02:07,400 --> 00:02:08,229 already have. 46 00:02:08,229 --> 00:02:09,800 Let me explain that. 47 00:02:09,800 --> 00:02:12,620 So what I'm saying is, look, our amount of decay is 48 00:02:12,620 --> 00:02:15,830 proportional to the amount of the substance that we already 49 00:02:15,830 --> 00:02:17,200 are dealing with. 50 00:02:17,200 --> 00:02:20,700 And just to maybe make that a little bit more intuitive, 51 00:02:20,700 --> 00:02:23,270 imagine a situation here where you have 1 52 00:02:23,270 --> 00:02:24,320 times 10 to the 9th. 53 00:02:24,320 --> 00:02:29,750 You have a billion carbon atoms. And let's say over here 54 00:02:29,750 --> 00:02:35,020 you have 1 times 10 to the 6th carbon atoms. And if you look 55 00:02:35,020 --> 00:02:38,260 at it at over some small period of time, let's say, if 56 00:02:38,260 --> 00:02:41,250 you look at it over one second, let's say our dt. 57 00:02:41,250 --> 00:02:43,800 dt as an infinitesimally small time, but let's say it's a 58 00:02:43,800 --> 00:02:44,670 change in time. 59 00:02:44,670 --> 00:02:45,610 It's a delta t. 60 00:02:45,610 --> 00:02:50,080 And let's say over one second, you observe that this sample 61 00:02:50,080 --> 00:02:54,720 had, I don't know, let's say you saw 1000 carbon particles. 62 00:02:54,720 --> 00:02:56,970 You really wouldn't see that with carbon-14, but this is 63 00:02:56,970 --> 00:02:59,840 just for the sake of our intuition. 64 00:02:59,840 --> 00:03:02,910 Let's say over one second you saw 1000 carbon particles per 65 00:03:02,910 --> 00:03:04,020 second here. 66 00:03:04,020 --> 00:03:06,990 Well here you have 1000th of the number particles in this 67 00:03:06,990 --> 00:03:08,600 sample as this one. 68 00:03:08,600 --> 00:03:11,340 So, for every thousand particles you saw decaying 69 00:03:11,340 --> 00:03:14,810 here, you'd really expect to see one carbon particle per 70 00:03:14,810 --> 00:03:15,380 second here. 71 00:03:15,380 --> 00:03:17,260 Just because you have a smaller amount. 72 00:03:17,260 --> 00:03:19,570 Now I don't know what the actual constant is. 73 00:03:19,570 --> 00:03:22,040 But we know that no matter what substance we're talking 74 00:03:22,040 --> 00:03:25,060 about, this constant is dependent on the substance. 75 00:03:25,060 --> 00:03:27,510 Carbon's going to be different from uranium, is going to be 76 00:03:27,510 --> 00:03:30,810 different from, you know, we looked at radon. 77 00:03:30,810 --> 00:03:32,400 They're all going to have different 78 00:03:32,400 --> 00:03:33,710 quantities right here. 79 00:03:33,710 --> 00:03:34,390 And we can see that. 80 00:03:34,390 --> 00:03:36,670 We'll actually do it in the next video, you can actually 81 00:03:36,670 --> 00:03:39,170 calculate this from the half-life. 82 00:03:39,170 --> 00:03:41,930 But the rate of change is always going to be dependent 83 00:03:41,930 --> 00:03:45,380 on the number of particles you have, right? 84 00:03:45,380 --> 00:03:46,950 I mean, we saw that here with half-life. 85 00:03:46,950 --> 00:03:50,340 When you have 1/2 the number of particles, 86 00:03:50,340 --> 00:03:53,270 you lose 1/2 as much. 87 00:03:53,270 --> 00:03:56,180 Here, if we start with 100 particles here, we went to 50 88 00:03:56,180 --> 00:04:00,070 particles, then we went to 25. 89 00:04:00,070 --> 00:04:03,115 When you start with 50, in a period of time you lose 25. 90 00:04:03,115 --> 00:04:06,230 When you start with 100, you lose 50. 91 00:04:06,230 --> 00:04:08,700 So clearly the amount you lose is dependent on the amount you 92 00:04:08,700 --> 00:04:10,400 started with, right? 93 00:04:10,400 --> 00:04:12,270 Over any fraction of time, and here it's 94 00:04:12,270 --> 00:04:13,840 a very small fraction. 95 00:04:13,840 --> 00:04:19,279 So what I set up here is really fairly simple, but it 96 00:04:19,279 --> 00:04:20,940 doesn't sound so simple to a lot of people if you say it's 97 00:04:20,940 --> 00:04:22,400 a differential equation. 98 00:04:22,400 --> 00:04:25,600 We can actually solve this using pretty straightforward 99 00:04:25,600 --> 00:04:26,860 techniques. 100 00:04:26,860 --> 00:04:30,750 This is actually a separation of variables problem. 101 00:04:30,750 --> 00:04:32,490 And so, what can we do? 102 00:04:32,490 --> 00:04:37,162 Let's divide both sides by N. 103 00:04:37,162 --> 00:04:39,920 We want to get all the N's on this side and all the t stuff 104 00:04:39,920 --> 00:04:41,200 on the other side. 105 00:04:41,200 --> 00:04:48,460 So if we have 1 over N, dN over dt is 106 00:04:48,460 --> 00:04:49,910 equal to minus lambda. 107 00:04:49,910 --> 00:04:53,560 I just divided both sides of this by N. 108 00:04:53,560 --> 00:04:57,230 And then I can multiply both sides of this by dt, and I get 109 00:04:57,230 --> 00:05:05,520 1 over N dN is equal to minus lambda dt. 110 00:05:05,520 --> 00:05:08,530 Now I can take the integral of both sides of this equation. 111 00:05:08,530 --> 00:05:11,110 112 00:05:11,110 --> 00:05:12,740 And what do I get? 113 00:05:12,740 --> 00:05:14,200 What's the antiderivative? 114 00:05:14,200 --> 00:05:16,370 I'm taking the indefinite integral or the 115 00:05:16,370 --> 00:05:16,540 antiderivative. 116 00:05:16,540 --> 00:05:19,930 What's the antiderivative of 1 over N? 117 00:05:19,930 --> 00:05:29,460 Well that's the natural log of N plus some constant-- I'll 118 00:05:29,460 --> 00:05:32,400 just do that in blue-- plus some constant. 119 00:05:32,400 --> 00:05:37,050 And then that equals-- What's the antiderivative of just 120 00:05:37,050 --> 00:05:37,570 some constant? 121 00:05:37,570 --> 00:05:40,880 Well it's just that constant times the 122 00:05:40,880 --> 00:05:41,980 derivative, the variable. 123 00:05:41,980 --> 00:05:43,360 We're taking the antiderivative 124 00:05:43,360 --> 00:05:43,725 with respect to. 125 00:05:43,725 --> 00:05:48,840 So minus lambda, times t, plus some constant. 126 00:05:48,840 --> 00:05:51,630 These are different constants, but they're arbitrary. 127 00:05:51,630 --> 00:05:53,930 So if we want, we can just subtract that constant from 128 00:05:53,930 --> 00:05:56,130 that constant, and put them all on one side and then we 129 00:05:56,130 --> 00:05:57,120 just get another constant. 130 00:05:57,120 --> 00:06:00,260 So this boils down to our solution to our differential 131 00:06:00,260 --> 00:06:06,490 equation is the natural log of N is equal to minus lambda-t, 132 00:06:06,490 --> 00:06:10,410 plus some other constant, I call it c3, it doesn't matter. 133 00:06:10,410 --> 00:06:14,110 And now if we want to just make this a function of N in 134 00:06:14,110 --> 00:06:19,460 terms of t, let's take both of these, or both take e to the 135 00:06:19,460 --> 00:06:20,920 power of both sides of this. 136 00:06:20,920 --> 00:06:24,350 You can view that as kind of the inverse natural log. 137 00:06:24,350 --> 00:06:29,150 So e to the power of ln of N, ln of N is just saying what 138 00:06:29,150 --> 00:06:31,420 power do you raise e to to get to N? 139 00:06:31,420 --> 00:06:34,720 So if you raise e to that power, you get N. 140 00:06:34,720 --> 00:06:39,120 So I'm just raising both sides of this equation. 141 00:06:39,120 --> 00:06:42,220 I'm raising e to both sides of this equation. 142 00:06:42,220 --> 00:06:44,650 e to the ln of N is just N. 143 00:06:44,650 --> 00:06:50,570 And that is equal to e to the minus lambda-t, plus c3. 144 00:06:50,570 --> 00:06:53,770 And now this can be rewritten as, N is equal to e to the 145 00:06:53,770 --> 00:06:58,350 minus lambda-t, times e to the c3. 146 00:06:58,350 --> 00:07:00,630 And now once again this is an arbitrary constant, so we can 147 00:07:00,630 --> 00:07:03,450 just really rename that as, I don't know, let me 148 00:07:03,450 --> 00:07:04,700 rename it as c4. 149 00:07:04,700 --> 00:07:07,200 150 00:07:07,200 --> 00:07:11,660 So, our solution to our differential equation, N, as a 151 00:07:11,660 --> 00:07:17,870 function of t, is equal to our c4 constant, c4e 152 00:07:17,870 --> 00:07:20,030 to the minus lambda-t. 153 00:07:20,030 --> 00:07:23,330 Now let's say, even better, let's say is N equals 0. 154 00:07:23,330 --> 00:07:26,400 Let's say that N equals 0. 155 00:07:26,400 --> 00:07:31,130 We have N sub 0 of our sample. 156 00:07:31,130 --> 00:07:32,680 That's how much we're starting off with. 157 00:07:32,680 --> 00:07:34,830 So let's see if we can substitute that into our 158 00:07:34,830 --> 00:07:37,990 equation to solve for c4. 159 00:07:37,990 --> 00:07:45,510 So we said N sub-0 is equal to, let's put 0 in here, so 160 00:07:45,510 --> 00:07:48,930 let's see, that's equal to N sub naught. 161 00:07:48,930 --> 00:07:56,750 And that's equal to c4 times e to the minus lambda, times 0. 162 00:07:56,750 --> 00:07:58,770 Well, minus anything times 0 is 0. 163 00:07:58,770 --> 00:08:00,300 So it's e to the 0. 164 00:08:00,300 --> 00:08:01,710 So that's just 1. 165 00:08:01,710 --> 00:08:04,760 So c4 is equal to N naught, our starting 166 00:08:04,760 --> 00:08:05,770 amount for the sample. 167 00:08:05,770 --> 00:08:09,020 So we've actually got an expression. 168 00:08:09,020 --> 00:08:12,560 We have the number of particles, or the amount as a 169 00:08:12,560 --> 00:08:16,080 function of t, is equal to the amount that we start off with, 170 00:08:16,080 --> 00:08:20,220 at time is equal to 0, times e to the minus 171 00:08:20,220 --> 00:08:23,190 lambda, times time. 172 00:08:23,190 --> 00:08:25,010 And we just have to be careful that we're always using the 173 00:08:25,010 --> 00:08:27,610 time constant when we solve for the different 174 00:08:27,610 --> 00:08:28,590 coefficients. 175 00:08:28,590 --> 00:08:30,830 So this seems all abstract. 176 00:08:30,830 --> 00:08:32,049 How does this relate to half-life? 177 00:08:32,049 --> 00:08:35,390 Well let's try to figure out this equation for carbon. 178 00:08:35,390 --> 00:08:37,190 This'll be true for anything where we 179 00:08:37,190 --> 00:08:38,200 have radioactive decay. 180 00:08:38,200 --> 00:08:41,150 If we actually had a plus sign here it'd be exponential 181 00:08:41,150 --> 00:08:43,039 growth as well. 182 00:08:43,039 --> 00:08:57,260 We know that carbon, c-14, has a 5,700-year half-life. 183 00:08:57,260 --> 00:09:00,060 So the way you could think about it, is if at time equals 184 00:09:00,060 --> 00:09:08,240 0 you start off with t-- So time equals 0. t equals-- let 185 00:09:08,240 --> 00:09:09,020 me write that down. 186 00:09:09,020 --> 00:09:14,000 If at N of 0 is equal to-- and we could write 187 00:09:14,000 --> 00:09:15,240 100 there if we want. 188 00:09:15,240 --> 00:09:16,090 Actually why don't we do that? 189 00:09:16,090 --> 00:09:18,530 If N of 0 we start off with 100. 190 00:09:18,530 --> 00:09:25,800 And then at N of 5,700 years-- so we're going to take t to be 191 00:09:25,800 --> 00:09:28,620 in years, you just have to be consistent with your units-- 192 00:09:28,620 --> 00:09:29,740 how much will we have left? 193 00:09:29,740 --> 00:09:31,440 We'll have 50 left. 194 00:09:31,440 --> 00:09:34,096 We could have written x and x over two here, and it would 195 00:09:34,096 --> 00:09:35,690 have all have worked out in the end. 196 00:09:35,690 --> 00:09:37,980 So let's see, let's apply that to this equation and try to 197 00:09:37,980 --> 00:09:40,460 solve this for lambda. 198 00:09:40,460 --> 00:09:42,770 So we know N of 0 is equal to 100. 199 00:09:42,770 --> 00:09:51,060 So we immediately know that we can write this equation as N 200 00:09:51,060 --> 00:09:57,520 of t is equal to 100e, to the minus lambda-t, at least in 201 00:09:57,520 --> 00:09:59,080 this exact circumstance. 202 00:09:59,080 --> 00:10:02,800 203 00:10:02,800 --> 00:10:10,450 And we also know that N of 5,700-- so that means, N of 204 00:10:10,450 --> 00:10:15,600 5,700-- that is equal to, we just said, that's one 205 00:10:15,600 --> 00:10:16,450 half-life away. 206 00:10:16,450 --> 00:10:19,020 So we have 1/2 as much of our compound left. 207 00:10:19,020 --> 00:10:25,560 That's equal to 50, which is equal to the 5,700th power 208 00:10:25,560 --> 00:10:26,830 times lambda. 209 00:10:26,830 --> 00:10:30,500 So it's equal to 100 times e, to the minus 210 00:10:30,500 --> 00:10:34,770 lambda, times 5,700. 211 00:10:34,770 --> 00:10:35,940 And now we just solve for lambda. 212 00:10:35,940 --> 00:10:38,240 Then we'll have a general equation for how much carbon 213 00:10:38,240 --> 00:10:40,470 we have at any given moment in time. 214 00:10:40,470 --> 00:10:44,850 So if you divide both sides of this by 100. 215 00:10:44,850 --> 00:10:46,160 What do we get? 216 00:10:46,160 --> 00:10:52,230 We get 0.5, we have 1/2, is equal to e to the-- let me 217 00:10:52,230 --> 00:10:56,200 just write minus 5,700 lambda, and then we could take the 218 00:10:56,200 --> 00:10:58,010 natural log of both sides. 219 00:10:58,010 --> 00:11:02,350 So then we get-- scroll down a bit-- the natural log of 1/2 220 00:11:02,350 --> 00:11:05,140 is equal to the-- the natural log of this is just minus 221 00:11:05,140 --> 00:11:07,890 5,700 lambda. 222 00:11:07,890 --> 00:11:10,510 To solve for lambda, you get lambda is equal to the natural 223 00:11:10,510 --> 00:11:16,210 log of 1/2, over minus 5,700. 224 00:11:16,210 --> 00:11:19,990 So let me see what that is. 225 00:11:19,990 --> 00:11:20,980 Let's see what that is. 226 00:11:20,980 --> 00:11:30,980 So 0.5 natural log is that, divided by minus 5,700. 227 00:11:30,980 --> 00:11:38,456 5,700 negative is equal to 1.2 times 10 to the negative 4. 228 00:11:38,456 --> 00:11:43,410 Is equal to 1.21 times 10 to the minus 4. 229 00:11:43,410 --> 00:11:45,370 So there you have it, we figured out our lambda. 230 00:11:45,370 --> 00:11:49,440 So the general equation for how much carbon-14 we can 231 00:11:49,440 --> 00:11:55,340 expect at any moment in time, t, where t is in years, is N 232 00:11:55,340 --> 00:11:58,340 of t is equal to the amount of carbon we start off with, 233 00:11:58,340 --> 00:12:01,280 times e to the minus lambda. 234 00:12:01,280 --> 00:12:04,780 The minus lambda is 1.21 times 10 to the minus 235 00:12:04,780 --> 00:12:08,350 4, times t in years. 236 00:12:08,350 --> 00:12:11,500 So now if you say after 1/2 a year, you just plug it in and, 237 00:12:11,500 --> 00:12:13,630 you have to tell me how much you started off with, and then 238 00:12:13,630 --> 00:12:15,870 I can tell you how much you have after 1/2 a year, or 239 00:12:15,870 --> 00:12:18,060 after a billion years, or after a gazillion years. 240 00:12:18,060 --> 00:12:19,360 And we'll do a lot more of these 241 00:12:19,360 --> 00:12:21,350 problems in the next video. 242 00:12:21,350 --> 00:00:00,000