1 00:00:00,000 --> 00:00:00,940 2 00:00:00,940 --> 00:00:04,310 After all the work we've been doing with fluids, you 3 00:00:04,310 --> 00:00:07,670 probably have a pretty good sense of what pressure is. 4 00:00:07,670 --> 00:00:10,110 Now let's think a little bit about what it really means, 5 00:00:10,110 --> 00:00:11,910 especially when we think about it in terms 6 00:00:11,910 --> 00:00:14,040 of a gas in a volume. 7 00:00:14,040 --> 00:00:15,070 Remember, what was the difference 8 00:00:15,070 --> 00:00:17,440 between a gas and a liquid? 9 00:00:17,440 --> 00:00:19,590 They're both fluids, they both take the shape of their 10 00:00:19,590 --> 00:00:24,070 containers, but a gas is compressible, while a liquid 11 00:00:24,070 --> 00:00:25,230 is incompressible. 12 00:00:25,230 --> 00:00:27,680 Let's start focusing on gases. 13 00:00:27,680 --> 00:00:39,120 Let's say I have a container, and I have a 14 00:00:39,120 --> 00:00:40,830 bunch of gas in it. 15 00:00:40,830 --> 00:00:42,430 What is a gas made of? 16 00:00:42,430 --> 00:00:45,190 It's just made up of a whole bunch of the molecules of the 17 00:00:45,190 --> 00:00:47,860 gas itself, and I'll draw each of the molecules with a little 18 00:00:47,860 --> 00:00:51,620 dot-- it's just going to have a bunch of molecules in it. 19 00:00:51,620 --> 00:00:54,770 There's many, many, many more than what I've drawn, but 20 00:00:54,770 --> 00:00:57,090 that's indicative, and they'll all be going in random 21 00:00:57,090 --> 00:01:02,440 directions-- this one might be going really fast in that 22 00:01:02,440 --> 00:01:04,349 direction, and that one might be going a little bit slower 23 00:01:04,349 --> 00:01:06,220 in that direction. 24 00:01:06,220 --> 00:01:09,130 They all have their own little velocity vectors, and they're 25 00:01:09,130 --> 00:01:11,970 always constantly bumping into each other, and bumping into 26 00:01:11,970 --> 00:01:14,510 the sides of the container, and ricocheting here and there 27 00:01:14,510 --> 00:01:17,030 and changing velocity. 28 00:01:17,030 --> 00:01:20,250 In general, especially at this level of physics, we assume 29 00:01:20,250 --> 00:01:26,410 that this is an ideal gas, that all of the bumps that 30 00:01:26,410 --> 00:01:28,040 occur, there's no loss of energy. 31 00:01:28,040 --> 00:01:31,710 Or essentially that they're all elastic bumps between the 32 00:01:31,710 --> 00:01:32,540 different molecules. 33 00:01:32,540 --> 00:01:36,620 There's no loss of momentum. 34 00:01:36,620 --> 00:01:39,280 Let's keep that in mind, and everything you're going to see 35 00:01:39,280 --> 00:01:42,280 in high school and on the AP test is going to deal with 36 00:01:42,280 --> 00:01:43,560 ideal gases. 37 00:01:43,560 --> 00:01:46,400 Let's think about what pressure 38 00:01:46,400 --> 00:01:47,740 means in this context. 39 00:01:47,740 --> 00:01:50,530 40 00:01:50,530 --> 00:01:53,350 A lot of what we think about pressure is something pushing 41 00:01:53,350 --> 00:01:55,110 on an area. 42 00:01:55,110 --> 00:01:56,930 If we think about pressure here-- let's pick 43 00:01:56,930 --> 00:01:57,840 an arbitrary area. 44 00:01:57,840 --> 00:02:00,770 Let's take this side. 45 00:02:00,770 --> 00:02:05,295 Let's take this surface of its container. 46 00:02:05,295 --> 00:02:09,870 47 00:02:09,870 --> 00:02:10,940 Where's the pressure going to be 48 00:02:10,940 --> 00:02:13,540 generated onto this surface? 49 00:02:13,540 --> 00:02:17,660 It's going to be generated by just the millions and billions 50 00:02:17,660 --> 00:02:20,040 and trillions of little bumps every time-- let 51 00:02:20,040 --> 00:02:21,850 me draw a side view. 52 00:02:21,850 --> 00:02:27,160 If this is the side view of the container, that same side, 53 00:02:27,160 --> 00:02:32,590 every second there's always these little molecules of gas 54 00:02:32,590 --> 00:02:34,720 moving around. 55 00:02:34,720 --> 00:02:37,930 If we pick an arbitrary period of time, they're always 56 00:02:37,930 --> 00:02:41,380 ricocheting off of the side. 57 00:02:41,380 --> 00:02:44,200 58 00:02:44,200 --> 00:02:48,000 We're looking at time over a super-small fraction of time. 59 00:02:48,000 --> 00:02:51,790 And over that period of time, this one might end up here, 60 00:02:51,790 --> 00:02:54,750 this one maybe bumped into it right after it ricocheted and 61 00:02:54,750 --> 00:02:59,400 came here, this one changes momentum and goes like that. 62 00:02:59,400 --> 00:03:01,140 This one might have already been going in that direction, 63 00:03:01,140 --> 00:03:02,640 and that one might ricochet. 64 00:03:02,640 --> 00:03:05,280 But what's happening is, at any given moment, since 65 00:03:05,280 --> 00:03:10,760 there's so many molecules, there's always going to be 66 00:03:10,760 --> 00:03:14,190 some molecules that are bumping into 67 00:03:14,190 --> 00:03:15,960 the side of the wall. 68 00:03:15,960 --> 00:03:18,275 When they bump, they have a change in momentum. 69 00:03:18,275 --> 00:03:21,520 70 00:03:21,520 --> 00:03:24,900 All force is change in momentum over time. 71 00:03:24,900 --> 00:03:30,960 72 00:03:30,960 --> 00:03:34,410 What I'm saying is that in any interval of time, over any 73 00:03:34,410 --> 00:03:37,070 period or any change in time, there's just going to be a 74 00:03:37,070 --> 00:03:41,910 bunch of particles that are changing their momentum on the 75 00:03:41,910 --> 00:03:45,500 side of this wall. 76 00:03:45,500 --> 00:03:48,250 That is going to generate force, and so if we think 77 00:03:48,250 --> 00:03:51,560 about how many on average-- because it's hard to keep 78 00:03:51,560 --> 00:03:55,720 track of each particle individually, and when we did 79 00:03:55,720 --> 00:03:58,670 kinematics and stuff, we'd keep track of the individual 80 00:03:58,670 --> 00:03:59,460 object at play. 81 00:03:59,460 --> 00:04:02,780 But when we're dealing with gases and things on a macro 82 00:04:02,780 --> 00:04:06,280 level, you can't keep track of any individual one, unless you 83 00:04:06,280 --> 00:04:08,830 have some kind of unbelievable supercomputer. 84 00:04:08,830 --> 00:04:14,490 We can say, on average, this many particles are changing 85 00:04:14,490 --> 00:04:17,240 momentum on this wall in this amount of time. 86 00:04:17,240 --> 00:04:20,890 And so the force exerted on this wall or this surface is 87 00:04:20,890 --> 00:04:22,670 going to be x. 88 00:04:22,670 --> 00:04:25,910 If we know what that force is, and we you know the area of 89 00:04:25,910 --> 00:04:30,090 the wall, we can figure out pressure, because pressure is 90 00:04:30,090 --> 00:04:36,560 equal to force divided by area. 91 00:04:36,560 --> 00:04:42,110 What does this help us with? 92 00:04:42,110 --> 00:04:44,150 I wanted to give you that intuition first, and now I'm 93 00:04:44,150 --> 00:04:49,710 just going to give you the one formula that you really just 94 00:04:49,710 --> 00:04:50,970 need to know in thermodynamics. 95 00:04:50,970 --> 00:04:56,430 And then as we go into the next few videos, I'll prove to 96 00:04:56,430 --> 00:04:57,750 you why it works, and hopefully give 97 00:04:57,750 --> 00:04:58,700 you more of an intuition. 98 00:04:58,700 --> 00:05:01,230 Now you understand, hopefully, what pressure means in the 99 00:05:01,230 --> 00:05:03,610 context of a gas in a container. 100 00:05:03,610 --> 00:05:09,910 With that out of the way, let me give you a formula. 101 00:05:09,910 --> 00:05:11,890 I hope by the end of this video you have the intuition 102 00:05:11,890 --> 00:05:14,520 for why this formula works. 103 00:05:14,520 --> 00:05:18,490 In general, if I have an ideal gas in a container, the 104 00:05:18,490 --> 00:05:23,630 pressure exerted on the gas-- on the side of the container, 105 00:05:23,630 --> 00:05:26,910 or actually even at any point within the gas, because it 106 00:05:26,910 --> 00:05:30,000 will all become homogeneous at some point-- and we'll talk 107 00:05:30,000 --> 00:05:33,160 about entropy in future videos-- but the pressure in 108 00:05:33,160 --> 00:05:36,920 the container and on its surface, times the volume of 109 00:05:36,920 --> 00:05:41,820 the container, is equal to some constant. 110 00:05:41,820 --> 00:05:44,230 We'll see in future videos that that constant is actually 111 00:05:44,230 --> 00:05:48,830 proportional to the average kinetic energy of the 112 00:05:48,830 --> 00:05:50,100 molecules bouncing around. 113 00:05:50,100 --> 00:05:51,240 That should make sense to you. 114 00:05:51,240 --> 00:05:56,495 If the molecules were moving around a lot faster, then you 115 00:05:56,495 --> 00:05:58,400 would have more kinetic energy, and then they would be 116 00:05:58,400 --> 00:06:00,880 changing momentum on the sides of the surface a lot more, so 117 00:06:00,880 --> 00:06:03,930 you would have more pressure. 118 00:06:03,930 --> 00:06:06,780 Let's see if we can get a little bit more intuition onto 119 00:06:06,780 --> 00:06:09,185 why pressure times volume is a constant. 120 00:06:09,185 --> 00:06:18,900 121 00:06:18,900 --> 00:06:24,180 Let's say I have a container now, and it's got a bunch of 122 00:06:24,180 --> 00:06:25,640 molecules of gas in it. 123 00:06:25,640 --> 00:06:28,850 124 00:06:28,850 --> 00:06:32,190 Just like I showed you in that last bit right before I 125 00:06:32,190 --> 00:06:35,260 erased, these are bouncing off of the sides 126 00:06:35,260 --> 00:06:36,510 at a certain rate. 127 00:06:36,510 --> 00:06:41,390 128 00:06:41,390 --> 00:06:42,950 Each of the molecules might have a different kinetic 129 00:06:42,950 --> 00:06:44,160 energy-- it's always changing, because they're always 130 00:06:44,160 --> 00:06:45,960 transferring momentum to each other. 131 00:06:45,960 --> 00:06:50,030 But on average, they all have a given kinetic energy, they 132 00:06:50,030 --> 00:06:52,420 keep bumping at a certain rate into the wall, and that 133 00:06:52,420 --> 00:06:53,880 determines the pressure. 134 00:06:53,880 --> 00:06:58,920 What happens if I were able to squeeze the box, and if I were 135 00:06:58,920 --> 00:07:03,860 able to decrease the volume of the box? 136 00:07:03,860 --> 00:07:07,310 137 00:07:07,310 --> 00:07:09,910 I just take that same box with the same number of molecules 138 00:07:09,910 --> 00:07:11,470 in it, but I squeeze. 139 00:07:11,470 --> 00:07:13,460 I make the volume of the box smaller-- 140 00:07:13,460 --> 00:07:15,940 what's going to happen? 141 00:07:15,940 --> 00:07:22,110 I have the same number of molecules in there, with the 142 00:07:22,110 --> 00:07:25,890 same kinetic energy, and on average, they're moving with 143 00:07:25,890 --> 00:07:26,830 the same velocities. 144 00:07:26,830 --> 00:07:29,300 So now what's going to happen? 145 00:07:29,300 --> 00:07:33,150 They're going to be hitting the sides more often-- at the 146 00:07:33,150 --> 00:07:36,370 same time here that this particle went bam, bam, now it 147 00:07:36,370 --> 00:07:38,680 could go bam, bam, bam. 148 00:07:38,680 --> 00:07:41,400 They're going to be hitting the sides more often, so 149 00:07:41,400 --> 00:07:44,280 you're going to have more changes in momentum, and so 150 00:07:44,280 --> 00:07:49,550 you're actually going to have each particle exert more force 151 00:07:49,550 --> 00:07:51,130 on each surface. 152 00:07:51,130 --> 00:07:53,250 Because it's going to be hitting them more often in a 153 00:07:53,250 --> 00:07:54,510 given amount of time. 154 00:07:54,510 --> 00:07:56,350 The surfaces themselves are smaller. 155 00:07:56,350 --> 00:07:59,540 You have more force on a surface, and on a smaller 156 00:07:59,540 --> 00:08:02,170 surface, you're going to have higher pressure. 157 00:08:02,170 --> 00:08:04,060 Hopefully, that gives you an intuition that if I had some 158 00:08:04,060 --> 00:08:06,900 amount of pressure in this situation-- if I squeeze the 159 00:08:06,900 --> 00:08:09,190 volume, the pressure increases. 160 00:08:09,190 --> 00:08:11,750 Another intuition-- if I have a balloon, 161 00:08:11,750 --> 00:08:12,940 what blows up a balloon? 162 00:08:12,940 --> 00:08:18,830 It's the internal air pressure of the helium, or your own 163 00:08:18,830 --> 00:08:21,320 exhales that you put into the balloon. 164 00:08:21,320 --> 00:08:24,000 The more and more you try to squeeze a balloon-- if you 165 00:08:24,000 --> 00:08:26,580 squeeze it from all directions, it gets harder and 166 00:08:26,580 --> 00:08:30,040 harder to do it, and that's because the pressure within 167 00:08:30,040 --> 00:08:35,289 the balloon increases as you decrease the volume. 168 00:08:35,289 --> 00:08:41,480 If volume goes down, pressure goes up, and that makes sense. 169 00:08:41,480 --> 00:08:43,669 That follows that when they multiply each other, you have 170 00:08:43,669 --> 00:08:45,130 to have a constant. 171 00:08:45,130 --> 00:08:47,050 Let's take the same example again, and what happens if you 172 00:08:47,050 --> 00:08:49,190 make the volume bigger? 173 00:08:49,190 --> 00:08:56,340 Let's say I have-- it's huge like that, and I should have 174 00:08:56,340 --> 00:08:58,890 done it more proportionally, but I think you get the idea. 175 00:08:58,890 --> 00:09:02,090 You have the same number of particles, and if I had a 176 00:09:02,090 --> 00:09:04,740 particle here, in some period of time it could have gone 177 00:09:04,740 --> 00:09:09,930 bam, bam, bam-- it could have hit the walls twice. 178 00:09:09,930 --> 00:09:12,420 Now, in this situation, with larger walls, it might just go 179 00:09:12,420 --> 00:09:15,300 bam, and in that same amount of time, it will maybe get 180 00:09:15,300 --> 00:09:17,150 here and won't even hit the other wall. 181 00:09:17,150 --> 00:09:19,670 The particles, on average, are going to be colliding with the 182 00:09:19,670 --> 00:09:22,600 wall less often, and the walls are going to have a larger 183 00:09:22,600 --> 00:09:24,390 area, as well. 184 00:09:24,390 --> 00:09:29,860 So in this case, when our volume goes up, the average 185 00:09:29,860 --> 00:09:35,520 pressure or the pressure in the container goes down. 186 00:09:35,520 --> 00:09:37,560 Hopefully, that gives you a little intuition, and so 187 00:09:37,560 --> 00:09:38,970 you'll never forget that pressure 188 00:09:38,970 --> 00:09:41,200 times volume is constant. 189 00:09:41,200 --> 00:09:44,590 And then we can use that to do some pretty common problems, 190 00:09:44,590 --> 00:09:46,110 which I'll do in the next video. 191 00:09:46,110 --> 00:09:46,917 I'm about to run out of time. 192 00:09:46,917 --> 00:09:48,167 See you soon. 193 00:09:48,167 --> 00:00:00,000