1 00:00:00,869 --> 00:00:04,166 - [Voiceover] If you took a glass of water and a needle, 2 00:00:04,166 --> 00:00:07,933 and you took that needle and you very carefully, 3 00:00:07,933 --> 00:00:11,635 very carefully dropped it on the water, it would stay there, 4 00:00:11,635 --> 00:00:14,600 and it's not because it's floating. 5 00:00:14,600 --> 00:00:16,400 This needle would not be floating on the water. 6 00:00:16,400 --> 00:00:18,666 This needle is more dense than water, 7 00:00:18,666 --> 00:00:21,280 and we know that if it's more dense, then it should sink. 8 00:00:21,280 --> 00:00:22,533 So, it's not floating. 9 00:00:22,533 --> 00:00:25,066 It's actually just sitting on the surface, 10 00:00:25,066 --> 00:00:27,033 because there's surface tension. 11 00:00:27,033 --> 00:00:29,133 Water is a liquid that's capable of having 12 00:00:29,133 --> 00:00:31,533 a significant amount of surface tension, 13 00:00:31,533 --> 00:00:33,433 and you know it's surface tension because 14 00:00:33,433 --> 00:00:37,533 if you were to come in here and exert a little force down, 15 00:00:37,533 --> 00:00:39,100 breaking the surface tension, 16 00:00:39,100 --> 00:00:42,103 or pushing this needle just below the surface, 17 00:00:42,103 --> 00:00:42,973 then it would sink. 18 00:00:42,973 --> 00:00:44,333 It would sink like a stone 19 00:00:44,333 --> 00:00:46,992 and just drop immediately to the bottom of the cup. 20 00:00:46,992 --> 00:00:50,000 So, why does water have this property of surface tension? 21 00:00:50,000 --> 00:00:52,700 It has to do with the fact that the water molecules 22 00:00:52,700 --> 00:00:56,200 within this liquid are attracted to each other. 23 00:00:56,200 --> 00:00:58,700 This water molecule can form hydrogen bonds 24 00:00:58,700 --> 00:01:00,966 with the other water molecules around it, 25 00:01:00,966 --> 00:01:04,599 and it gets pulled toward them, and there's a term for this. 26 00:01:04,599 --> 00:01:06,800 We call this cohesion. 27 00:01:06,800 --> 00:01:09,963 So, the fact that water molecules and other liquid molecules 28 00:01:09,963 --> 00:01:13,933 are attracted to each other is called cohesion. 29 00:01:13,933 --> 00:01:15,894 But what does this have to do with surface tension? 30 00:01:15,894 --> 00:01:19,200 Well, the key is these water molecules 31 00:01:19,200 --> 00:01:20,661 would like to bunch together. 32 00:01:20,661 --> 00:01:22,563 They want to group together, if they can. 33 00:01:22,563 --> 00:01:24,833 So, what would this water molecule do? 34 00:01:24,833 --> 00:01:26,051 I mean, which way is he going to go? 35 00:01:26,051 --> 00:01:28,171 How does he pick which one to group with? 36 00:01:28,171 --> 00:01:28,779 That's a problem. 37 00:01:28,779 --> 00:01:32,033 Here in the bulk of the liquid, he can't decide, 38 00:01:32,033 --> 00:01:34,996 or in other words, let's just say 39 00:01:34,996 --> 00:01:38,433 he got pulled toward this molecule. 40 00:01:38,433 --> 00:01:41,900 Well, it's also getting pulled to the left by all of this, 41 00:01:41,900 --> 00:01:44,866 by this one pulling it back to its original position. 42 00:01:44,866 --> 00:01:47,450 This one's pulling it back to its original position, 43 00:01:47,450 --> 00:01:50,600 because there will be a component of that force 44 00:01:50,600 --> 00:01:54,833 that will point in the direction of its original position, 45 00:01:54,833 --> 00:01:56,566 as well as this one to the left. 46 00:01:56,566 --> 00:01:58,133 So, these are restricted. 47 00:01:58,133 --> 00:02:00,200 These molecules here in the bulk of the liquid 48 00:02:00,200 --> 00:02:03,833 have too many other water molecules around them 49 00:02:03,833 --> 00:02:05,520 dictating where they need to be, 50 00:02:05,520 --> 00:02:07,467 because if they tried to get displaced, 51 00:02:07,467 --> 00:02:09,586 it'd pull them back to that position. 52 00:02:09,586 --> 00:02:12,166 However, at the surface 53 00:02:12,166 --> 00:02:14,040 there's no water molecules above them. 54 00:02:14,040 --> 00:02:15,067 These are freer. 55 00:02:15,067 --> 00:02:16,101 They're less restricted. 56 00:02:16,101 --> 00:02:19,166 So, that allows these water molecules on the surface 57 00:02:19,166 --> 00:02:22,000 to group together a little better, 58 00:02:22,000 --> 00:02:27,000 form stronger tighter bonds, closer spacing at the surface 59 00:02:27,000 --> 00:02:29,500 in such a way that they form a tension 60 00:02:29,500 --> 00:02:31,681 that's not present in the bulk of the liquid. 61 00:02:31,681 --> 00:02:33,866 Yes, these water molecules down below 62 00:02:33,866 --> 00:02:36,356 will prevent them from just grouping into 63 00:02:36,356 --> 00:02:38,096 one big clump in the center, 64 00:02:38,096 --> 00:02:39,766 but since they're less restricted, 65 00:02:39,766 --> 00:02:43,000 they can form these tighter bonds here at the surface, 66 00:02:43,000 --> 00:02:46,800 and this allows it to support a pressure from above. 67 00:02:46,800 --> 00:02:49,066 So, this allows it to support a certain amount of weight, 68 00:02:49,066 --> 00:02:51,617 which allows the needle to rest on the surface. 69 00:02:51,617 --> 00:02:54,607 A few practical applications of this, one clinical. 70 00:02:54,607 --> 00:02:56,658 If there's bile present in urine, 71 00:02:56,658 --> 00:02:59,400 you can detect its presence because it lowers 72 00:02:59,400 --> 00:03:02,512 the surface tension of urine. 73 00:03:02,512 --> 00:03:04,530 So, it gives you a test of whether the liver 74 00:03:04,530 --> 00:03:06,869 is metabolizing things the way it should. 75 00:03:06,869 --> 00:03:09,800 Another application is if you go camping, 76 00:03:09,800 --> 00:03:10,813 and you're in the tent. 77 00:03:10,813 --> 00:03:15,466 It's raining, and the tent gets rain drops on it. 78 00:03:15,466 --> 00:03:18,689 Most tents will keep the water from seeping through, 79 00:03:18,689 --> 00:03:20,733 but you're going to be tempted. 80 00:03:20,733 --> 00:03:21,807 You're going to be sitting in here. 81 00:03:21,807 --> 00:03:23,315 You're going to be like, that looks cool, 82 00:03:23,315 --> 00:03:24,474 and you're going to touch it, 83 00:03:24,474 --> 00:03:26,027 but you're not supposed to touch it, 84 00:03:26,027 --> 00:03:27,466 because as soon as you touch it, 85 00:03:27,466 --> 00:03:29,233 you may break the surface tension, 86 00:03:29,233 --> 00:03:31,066 and once you break the surface tension, 87 00:03:31,066 --> 00:03:32,833 that water is dripping into your tent 88 00:03:32,833 --> 00:03:34,633 from that spot that you touched it, 89 00:03:34,633 --> 00:03:37,300 and you're probably not going to have a good night. 90 00:03:37,300 --> 00:03:40,400 So, resist the urge to break the surface tension 91 00:03:40,400 --> 00:03:41,930 on your tent if it's raining out. 92 00:03:41,930 --> 00:03:44,433 And when you wash your hands, when we use detergents. 93 00:03:44,433 --> 00:03:46,486 If you washed your hands with just regular water 94 00:03:46,486 --> 00:03:50,733 and that's it, sometimes the surface tension's too great. 95 00:03:50,733 --> 00:03:53,279 These water molecules are too bound to each other. 96 00:03:53,279 --> 00:03:54,849 They form too big of a clump. 97 00:03:54,849 --> 00:03:55,676 It doesn't look like it. 98 00:03:55,676 --> 00:03:58,900 It looks perfectly smooth, but on a microscopic level, 99 00:03:58,900 --> 00:04:02,700 the water's not as diffuse as it could be. 100 00:04:02,700 --> 00:04:05,684 It's forming these clumps, because the water has cohesion, 101 00:04:05,684 --> 00:04:10,000 and it joins together, but if you add a little soap 102 00:04:10,000 --> 00:04:13,133 to the scenario, that breaks the surface tension. 103 00:04:13,133 --> 00:04:14,500 It lowers the surface tension, 104 00:04:14,500 --> 00:04:16,233 which means these water molecules 105 00:04:16,233 --> 00:04:18,100 don't clump together as much, 106 00:04:18,100 --> 00:04:19,600 and if they're not clumping together, 107 00:04:19,600 --> 00:04:22,065 they can get into the small cracks, 108 00:04:22,065 --> 00:04:24,933 which kicks out the dirt in your hands, 109 00:04:24,933 --> 00:04:26,869 and this water is better able to penetrate 110 00:04:26,869 --> 00:04:29,940 into the smaller cracks and get where it needs to go. 111 00:04:29,940 --> 00:04:32,933 So, surface tension is due to cohesion 112 00:04:32,933 --> 00:04:36,366 between the water molecules at the surface of a liquid, 113 00:04:36,366 --> 00:04:39,619 but water molecules aren't just attracted to each other. 114 00:04:39,619 --> 00:04:42,043 They're actually attracted to the container too 115 00:04:42,043 --> 00:04:45,135 and other materials, and that's called adhesion. 116 00:04:45,135 --> 00:04:48,150 So, the fact that water molecules 117 00:04:48,150 --> 00:04:52,500 are attracted to other materials as well is called adhesion. 118 00:04:52,500 --> 00:04:54,600 So, what happens is, this water molecule 119 00:04:54,600 --> 00:04:56,817 isn't just attracted to the other water molecules, 120 00:04:56,817 --> 00:04:58,102 it's attracted to the wall, 121 00:04:58,102 --> 00:05:01,900 and these water molecules climb the wall a little bit. 122 00:05:01,900 --> 00:05:02,866 So, that's why you'll see 123 00:05:02,866 --> 00:05:04,800 when you fill a container with water, 124 00:05:04,800 --> 00:05:08,300 or you're measuring an amount of liquid in a small burette, 125 00:05:08,300 --> 00:05:10,833 it's not perfectly level at the surface. 126 00:05:10,833 --> 00:05:14,633 It actually forms this kind of shape like that. 127 00:05:14,633 --> 00:05:17,256 This is exaggerated, but the sides will be 128 00:05:17,256 --> 00:05:18,655 a little higher than the middle. 129 00:05:18,655 --> 00:05:20,400 So, you have to be careful when you're measuring. 130 00:05:20,400 --> 00:05:23,356 This is usually called the meniscus, 131 00:05:23,356 --> 00:05:25,900 and it's caused by the adhesion, 132 00:05:25,900 --> 00:05:27,409 the attraction of water molecules 133 00:05:27,409 --> 00:05:29,276 to the container that it's in. 134 00:05:29,276 --> 00:05:32,484 This adhesive force, this adhesion force, is important. 135 00:05:32,484 --> 00:05:34,786 It causes something called capillary action. 136 00:05:34,786 --> 00:05:36,919 So, let me get rid of this. 137 00:05:36,919 --> 00:05:40,799 If you have a container with liquid, or say water, 138 00:05:40,799 --> 00:05:42,648 and you took another container. 139 00:05:42,648 --> 00:05:44,633 You put it in here like a straw. 140 00:05:44,633 --> 00:05:47,000 If you just stick it in, what you'll see is that 141 00:05:47,000 --> 00:05:50,004 because the liquid is attracted to the walls 142 00:05:50,004 --> 00:05:53,766 of this inner container, it doesn't just stay at this level, 143 00:05:53,766 --> 00:05:55,566 it'll rise above. 144 00:05:55,566 --> 00:05:59,367 It pulls this up a little bit above 145 00:05:59,367 --> 00:06:02,017 the surface level of the water. 146 00:06:02,017 --> 00:06:05,000 And if you took an even smaller diameter tube 147 00:06:05,000 --> 00:06:07,266 and put it in there, the smaller the tube 148 00:06:07,266 --> 00:06:10,538 the greater this effect, and you'd get this water rising 149 00:06:10,538 --> 00:06:14,300 to an even higher level within this tube, 150 00:06:14,300 --> 00:06:17,733 due to the adhesion to the walls of this container. 151 00:06:17,733 --> 00:06:21,133 And the name for this effect is capillary action, 152 00:06:21,133 --> 00:06:23,933 which is important in a variety of biological 153 00:06:23,933 --> 00:06:27,979 and non-biological examples where fluid is being aided 154 00:06:27,979 --> 00:06:32,176 in transport partially by the attraction to the walls 155 00:06:32,176 --> 00:00:00,000 of the container or the tube that it's flowing in.